Phase Formation of Ba(Ce1-xZrx)0.90Y0.1O3-δ Prepared by a Modified Sol-Gel Method
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چکیده
The powders of Ba(Ce1-xZrx)0.90Y0.1O3-δ (BCZY) with 0.2 ≤ x ≤ 0.6 have been prepared by a modified sol-gel method. Triethylenetetramine (TETA) was employed as chelating agent. Phase formation of calcined powders at 1100C and sintered pellets at 1400C of BCZY were examined by an X-ray diffractrometer (XRD). XRD results showed the calcined powder and sintered pellet formed a single perovskite phase over the entire range of x values. As the amount of zirconium substitution (x values) increase, the main peaks are shifted to the higher 2theta values which suggest a complete substitution of zirconium into cerium sites. All the obtained calcined powders and sintered pellets possess cubic structure (Pm3m) at all x values. Keywords—Structure, phase formation, modified sol-gel, ceratezirconate electrolye, XRD.
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